A new modification of oxonium trimetaphosphimate monohydrate
نویسندگان
چکیده
Abstract Metaphosphimates are possible precursors for oxonitridophosphates. A new polymorph of trimetaphosphimic acid, in fact an oxonium trimetaphosphimate monohydrate, crystallizes the monoclinic space group P 2 1 / c . It exhibits coin‐roll‐like stacks H (PO NH) 3 − anions a rectangular pattern, whereas these form hexagonal arrangement known polymorph. Ring conformation analysis reveals state between boat and twist conformations, closer to conformation. Temperature‐dependent powder diffraction shows decomposition upon heating ca. 100 °C.
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ژورنال
عنوان ژورنال: Zeitschrift für anorganische und allgemeine Chemie
سال: 2022
ISSN: ['0044-2313', '1521-3749']
DOI: https://doi.org/10.1002/zaac.202200259